Words that have identical vowel-based rhyme sounds in the tonic syllable. Moreover, that tonic syllable must start with a different consonantal sound.
There are no pure rhymes for "p w".
Words that have a pure rhyme on their last syllable only.
tew
    Donahue
      Donoghue
        Donohue
          O'Donoghue
            Donahue
              Donoghue
                Donohue

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                  Words that "almost" rhyme on the vowel-based rhyme sound of the stressed syllable like: be/eat or maybe/shapely.
                  emu
                    preview
                      rearview
                        feverfew
                          Vibhu
                            Hebrew
                              Mogadishu
                                Rhymes made up of more than one word. For instance, "jealous" and "tell us" or "shaky" and "make me."