Words that have identical vowel-based rhyme sounds in the tonic syllable. Moreover, that tonic syllable must start with a different consonantal sound.
There are no pure rhymes for "pace face".
Words that have a pure rhyme on their last syllable only.
ace
    base
      bass
        brace
          caisse
            case
              chace
                chase
                  dace
                    face
                      glace
                        grace
                          lace
                            mace
                              nace
                                pace
                                  place
                                    race
                                      space
                                        trace
                                          vase
                                            apace
                                              debase
                                                deface
                                                  disgrace
                                                    displace
                                                      efface
                                                        embrace
                                                          encase
                                                            erase
                                                              incase
                                                                lambastes
                                                                  misplace
                                                                    replace
                                                                      retrace
                                                                        ligase
                                                                          interlace
                                                                            Cayce
                                                                              Heyse
                                                                                Wace
                                                                                  airspace
                                                                                    typeface
                                                                                      outpace
                                                                                        showplace
                                                                                          workplace
                                                                                            someplace
                                                                                              boldface
                                                                                                birthplace
                                                                                                  briefcase
                                                                                                    showcase
                                                                                                      shoelace
                                                                                                        lactase
                                                                                                          airbase
                                                                                                            staircase
                                                                                                              maltase
                                                                                                                bookcase
                                                                                                                  footrace
                                                                                                                    suitcase
                                                                                                                      wheelbase
                                                                                                                        hyperspace
                                                                                                                          cyberspace
                                                                                                                            diastase
                                                                                                                              database
                                                                                                                                interface
                                                                                                                                  outerspace
                                                                                                                                    anyplace
                                                                                                                                      aerospace
                                                                                                                                        interface
                                                                                                                                          everyplace
                                                                                                                                            diabase
                                                                                                                                              fireplace
                                                                                                                                                database
                                                                                                                                                  carapace
                                                                                                                                                    steeplechase
                                                                                                                                                      carapace
                                                                                                                                                        commonplace
                                                                                                                                                          marketplace
                                                                                                                                                            marketplace
                                                                                                                                                              orthoclase
                                                                                                                                                                reiterates
                                                                                                                                                                  plagioclase
                                                                                                                                                                    streptokinase
                                                                                                                                                                      polymerase
                                                                                                                                                                        Myspace
                                                                                                                                                                          Lovelace
                                                                                                                                                                            Borges
                                                                                                                                                                              DNase
                                                                                                                                                                                Scarface
                                                                                                                                                                                  Words that "almost" rhyme on the vowel-based rhyme sound of the stressed syllable like: be/eat or maybe/shapely.
                                                                                                                                                                                  database
                                                                                                                                                                                    plagioclase
                                                                                                                                                                                      Rhymes made up of more than one word. For instance, "jealous" and "tell us" or "shaky" and "make me."