Words that have identical vowel-based rhyme sounds in the tonic syllable. Moreover, that tonic syllable must start with a different consonantal sound.
There are no pure rhymes for "r j".
Words that have a pure rhyme on their last syllable only.
ohare
    Cesare
      LaBarre
        Lazare
          parte
            Duarte
              caraway
                carraway

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                  Words that "almost" rhyme on the vowel-based rhyme sound of the stressed syllable like: be/eat or maybe/shapely.
                  ohare
                    Cesare
                      LaBarre
                        Lazare
                          parte
                            Duarte
                              andre
                                Andrej

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                                  Rhymes made up of more than one word. For instance, "jealous" and "tell us" or "shaky" and "make me."