Words that have identical vowel-based rhyme sounds in the tonic syllable. Moreover, that tonic syllable must start with a different consonantal sound.
There are no pure rhymes for "r rated".
Words that have a pure rhyme on their last syllable only.
charted
    hearted
      parted
        started
          departed
            cooperated
              operated
                clotted
                  dotted
                    plotted
                      spotted
                        trotted

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                          Words that "almost" rhyme on the vowel-based rhyme sound of the stressed syllable like: be/eat or maybe/shapely.
                          charted
                            hearted
                              parted
                                started
                                  departed
                                    cooperated
                                      operated
                                        clotted
                                          dotted
                                            plotted
                                              spotted
                                                trotted

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                                                  Rhymes made up of more than one word. For instance, "jealous" and "tell us" or "shaky" and "make me."