Words that have identical vowel-based rhyme sounds in the tonic syllable. Moreover, that tonic syllable must start with a different consonantal sound.
There are no pure rhymes for "r why".
Words that have a pure rhyme on their last syllable only.
glorify
    horrify
      clarify
        rarefy
          terrify
            verify
              gratify
                ratify
                  stratify

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                    Words that "almost" rhyme on the vowel-based rhyme sound of the stressed syllable like: be/eat or maybe/shapely.
                    mollify
                      qualify
                        disqualify
                          requalify
                            occupy
                              preoccupy
                                potpie
                                  botfly
                                    quantify
                                      occuli
                                        quantify
                                          modify
                                            ossify
                                              octopi
                                                personify
                                                  detoxify
                                                    Popeye
                                                      Claramae
                                                        Molokai
                                                          Rhymes made up of more than one word. For instance, "jealous" and "tell us" or "shaky" and "make me."