Words that have identical vowel-based rhyme sounds in the tonic syllable. Moreover, that tonic syllable must start with a different consonantal sound.
There are no pure rhymes for "nachos".
Words that have a pure rhyme on their last syllable only.
honchos
    honchoes
      llanos
        Castellanos
          Chicanos
            Lozano's
              Romano's
                Serrano's
                  tacos
                    Rocco's

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                      Words that "almost" rhyme on the vowel-based rhyme sound of the stressed syllable like: be/eat or maybe/shapely.
                      llanos
                        Castellanos
                          Chicanos
                            Lozano's
                              Romano's
                                Serrano's
                                  tacos
                                    Rocco's
                                      follows
                                        hollows
                                          swallows
                                            Apollo's
                                              Palos

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                                                Rhymes made up of more than one word. For instance, "jealous" and "tell us" or "shaky" and "make me."