Words that have identical vowel-based rhyme sounds in the tonic syllable. Moreover, that tonic syllable must start with a different consonantal sound.
deco
    echo
      eco
        gecko
          hecco
            seco
              zydeco
                Gekko
                  Greco
                    Words that have a pure rhyme on their last syllable only.
                    alco
                      palco
                        Balko
                          Falco
                            fiasco
                              Casco
                                Glasgow
                                  Glassco
                                    Lasko
                                      Pascoe
                                        Tabasco
                                          ancho
                                            rancho
                                              Pancho

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                                                Words that "almost" rhyme on the vowel-based rhyme sound of the stressed syllable like: be/eat or maybe/shapely.
                                                Mexico
                                                  Texaco
                                                    telco
                                                      Delco
                                                        Elco
                                                          Elko
                                                            fresco
                                                              Francesco
                                                                Genesco
                                                                  Lesko
                                                                    Moresco
                                                                      Tedesco
                                                                        UNESCO
                                                                          Wesco
                                                                            Tesco

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                                                                              Rhymes made up of more than one word. For instance, "jealous" and "tell us" or "shaky" and "make me."